iapws-if97 2.0.2 → 2.1.1

This diff represents the content of publicly available package versions that have been released to one of the supported registries. The information contained in this diff is provided for informational purposes only and reflects changes between package versions as they appear in their respective public registries.
Files changed (69) hide show
  1. package/CHANGELOG.md +8 -0
  2. package/README.md +33 -65
  3. package/dist/backward/hs.d.ts.map +1 -1
  4. package/dist/backward/hs.js +28 -42
  5. package/dist/backward/hs.js.map +1 -1
  6. package/dist/backward/ph.d.ts.map +1 -1
  7. package/dist/backward/ph.js +24 -5
  8. package/dist/backward/ph.js.map +1 -1
  9. package/dist/backward/ps.d.ts.map +1 -1
  10. package/dist/backward/ps.js +24 -5
  11. package/dist/backward/ps.js.map +1 -1
  12. package/dist/backward/solution-validation.d.ts +13 -0
  13. package/dist/backward/solution-validation.d.ts.map +1 -0
  14. package/dist/backward/solution-validation.js +85 -0
  15. package/dist/backward/solution-validation.js.map +1 -0
  16. package/dist/backward/th.d.ts.map +1 -1
  17. package/dist/backward/th.js +35 -5
  18. package/dist/backward/th.js.map +1 -1
  19. package/dist/backward/tolerances.d.ts +6 -0
  20. package/dist/backward/tolerances.d.ts.map +1 -0
  21. package/dist/backward/tolerances.js +21 -0
  22. package/dist/backward/tolerances.js.map +1 -0
  23. package/dist/backward/ts.d.ts.map +1 -1
  24. package/dist/backward/ts.js +35 -5
  25. package/dist/backward/ts.js.map +1 -1
  26. package/dist/constants.d.ts +34 -12
  27. package/dist/constants.d.ts.map +1 -1
  28. package/dist/constants.js +43 -13
  29. package/dist/constants.js.map +1 -1
  30. package/dist/core/region-detector.d.ts.map +1 -1
  31. package/dist/core/region-detector.js +56 -12
  32. package/dist/core/region-detector.js.map +1 -1
  33. package/dist/core/solver.d.ts.map +1 -1
  34. package/dist/core/solver.js +10 -4
  35. package/dist/core/solver.js.map +1 -1
  36. package/dist/regions/region3-subregions.d.ts +6 -2
  37. package/dist/regions/region3-subregions.d.ts.map +1 -1
  38. package/dist/regions/region3-subregions.js +15 -10
  39. package/dist/regions/region3-subregions.js.map +1 -1
  40. package/dist/regions/region3.d.ts.map +1 -1
  41. package/dist/regions/region3.js +3 -0
  42. package/dist/regions/region3.js.map +1 -1
  43. package/dist/regions/region4.d.ts +3 -1
  44. package/dist/regions/region4.d.ts.map +1 -1
  45. package/dist/regions/region4.js +9 -6
  46. package/dist/regions/region4.js.map +1 -1
  47. package/dist/saturation/common.d.ts.map +1 -1
  48. package/dist/saturation/common.js +23 -11
  49. package/dist/saturation/common.js.map +1 -1
  50. package/dist/saturation/region4-boundaries.d.ts +14 -0
  51. package/dist/saturation/region4-boundaries.d.ts.map +1 -0
  52. package/dist/saturation/region4-boundaries.js +79 -0
  53. package/dist/saturation/region4-boundaries.js.map +1 -0
  54. package/dist/saturation/region4-hs.d.ts +3 -0
  55. package/dist/saturation/region4-hs.d.ts.map +1 -0
  56. package/dist/saturation/region4-hs.js +82 -0
  57. package/dist/saturation/region4-hs.js.map +1 -0
  58. package/dist/saturation/two-phase.d.ts.map +1 -1
  59. package/dist/saturation/two-phase.js +4 -9
  60. package/dist/saturation/two-phase.js.map +1 -1
  61. package/dist/saturation.d.ts +6 -1
  62. package/dist/saturation.d.ts.map +1 -1
  63. package/dist/saturation.js +6 -1
  64. package/dist/saturation.js.map +1 -1
  65. package/dist/types.d.ts +8 -8
  66. package/dist/types.d.ts.map +1 -1
  67. package/dist/types.js +1 -1
  68. package/dist/types.js.map +1 -1
  69. package/package.json +1 -1
package/dist/backward/ps.js.map CHANGED
@@ -1 +1 @@
1
- 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1
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package/dist/backward/solution-validation.d.ts ADDED
@@ -0,0 +1,13 @@
1
+ import type { BasicProperties } from '../types.js';
2
+ import { Region } from '../types.js';
3
+ export interface BackwardConstraint {
4
+ label: 'pressure' | 'temperature' | 'enthalpy' | 'entropy';
5
+ expected: number;
6
+ tolerance?: number;
7
+ }
8
+ export interface BackwardValidationOptions {
9
+ solverName: string;
10
+ expectedRegion?: Region;
11
+ }
12
+ export declare function validateBackwardState(state: BasicProperties, constraints: readonly BackwardConstraint[], options: BackwardValidationOptions): BasicProperties;
13
+ //# sourceMappingURL=solution-validation.d.ts.map
package/dist/backward/solution-validation.d.ts.map ADDED
@@ -0,0 +1 @@
1
+ {"version":3,"file":"solution-validation.d.ts","sourceRoot":"","sources":["../../src/backward/solution-validation.ts"],"names":[],"mappings":"AAGA,OAAO,KAAK,EAAE,eAAe,EAAE,MAAM,aAAa,CAAC;AACnD,OAAO,EAAa,MAAM,EAAE,MAAM,aAAa,CAAC;AAMhD,MAAM,WAAW,kBAAkB;IACjC,KAAK,EAAE,UAAU,GAAG,aAAa,GAAG,UAAU,GAAG,SAAS,CAAC;IAC3D,QAAQ,EAAE,MAAM,CAAC;IACjB,SAAS,CAAC,EAAE,MAAM,CAAC;CACpB;AAED,MAAM,WAAW,yBAAyB;IACxC,UAAU,EAAE,MAAM,CAAC;IACnB,cAAc,CAAC,EAAE,MAAM,CAAC;CACzB;AAqGD,wBAAgB,qBAAqB,CACnC,KAAK,EAAE,eAAe,EACtB,WAAW,EAAE,SAAS,kBAAkB,EAAE,EAC1C,OAAO,EAAE,yBAAyB,GACjC,eAAe,CAKjB"}
package/dist/backward/solution-validation.js ADDED
@@ -0,0 +1,85 @@
1
+ import * as C from '../constants.js';
2
+ import { detectRegionPT } from '../core/region-detector.js';
3
+ import { saturationPressure } from '../regions/region4.js';
4
+ import { IF97Error, Region } from '../types.js';
5
+ import { backwardConstraintTolerance, region4SaturationPressureTolerance, } from './tolerances.js';
6
+ function propertyValue(state, label) {
7
+ switch (label) {
8
+ case 'pressure':
9
+ return state.pressure;
10
+ case 'temperature':
11
+ return state.temperature;
12
+ case 'enthalpy':
13
+ return state.enthalpy;
14
+ case 'entropy':
15
+ return state.entropy;
16
+ default:
17
+ return Number.NaN;
18
+ }
19
+ }
20
+ function validateBasicEnvelope(state, solverName) {
21
+ if (!Number.isFinite(state.pressure) || !Number.isFinite(state.temperature) ||
22
+ !Number.isFinite(state.specificVolume) || state.specificVolume <= 0) {
23
+ throw new IF97Error(`${solverName} produced an invalid thermodynamic state`);
24
+ }
25
+ if (state.pressure < C.P_MIN || state.pressure > C.P_MAX ||
26
+ state.temperature < C.T_MIN || state.temperature > C.T_MAX) {
27
+ throw new IF97Error(`${solverName} produced a state outside the IF97 PT envelope`);
28
+ }
29
+ }
30
+ function validateRegionConsistency(state, solverName, expectedRegion) {
31
+ if (expectedRegion !== undefined && state.region !== expectedRegion) {
32
+ throw new IF97Error(`${solverName} returned Region ${state.region}, expected Region ${expectedRegion}`);
33
+ }
34
+ if (state.region === Region.Region4) {
35
+ if (state.quality === null || !Number.isFinite(state.quality) || state.quality < 0 || state.quality > 1) {
36
+ throw new IF97Error(`${solverName} produced an invalid Region 4 quality`);
37
+ }
38
+ const psat = saturationPressure(state.temperature);
39
+ const pTolerance = region4SaturationPressureTolerance(state.pressure);
40
+ if (Math.abs(psat - state.pressure) > pTolerance) {
41
+ throw new IF97Error(`${solverName} produced a Region 4 state off the saturation curve`);
42
+ }
43
+ return;
44
+ }
45
+ const detectedRegion = detectRegionPT(state.pressure, state.temperature);
46
+ if (detectedRegion !== state.region) {
47
+ throw new IF97Error(`${solverName} produced a PT state in Region ${detectedRegion}, not Region ${state.region}`);
48
+ }
49
+ }
50
+ function validateConstraints(state, constraints, solverName) {
51
+ for (const constraint of constraints) {
52
+ const actual = propertyValue(state, constraint.label);
53
+ const tolerance = constraint.tolerance ?? backwardConstraintTolerance(constraint.label, constraint.expected);
54
+ if (Math.abs(actual - constraint.expected) > tolerance) {
55
+ throw new IF97Error(`${solverName} failed to match ${constraint.label}: expected ${constraint.expected}, got ${actual}`);
56
+ }
57
+ }
58
+ }
59
+ function withExactConstraints(state, constraints) {
60
+ const normalized = { ...state };
61
+ for (const constraint of constraints) {
62
+ switch (constraint.label) {
63
+ case 'pressure':
64
+ normalized.pressure = Object.is(constraint.expected, -0) ? 0 : constraint.expected;
65
+ break;
66
+ case 'temperature':
67
+ normalized.temperature = Object.is(constraint.expected, -0) ? 0 : constraint.expected;
68
+ break;
69
+ case 'enthalpy':
70
+ normalized.enthalpy = Object.is(constraint.expected, -0) ? 0 : constraint.expected;
71
+ break;
72
+ case 'entropy':
73
+ normalized.entropy = Object.is(constraint.expected, -0) ? 0 : constraint.expected;
74
+ break;
75
+ }
76
+ }
77
+ return normalized;
78
+ }
79
+ export function validateBackwardState(state, constraints, options) {
80
+ validateBasicEnvelope(state, options.solverName);
81
+ validateRegionConsistency(state, options.solverName, options.expectedRegion);
82
+ validateConstraints(state, constraints, options.solverName);
83
+ return withExactConstraints(state, constraints);
84
+ }
85
+ //# sourceMappingURL=solution-validation.js.map
package/dist/backward/solution-validation.js.map ADDED
@@ -0,0 +1 @@
1
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package/dist/backward/th.d.ts.map CHANGED
@@ -1 +1 @@
1
- {"version":3,"file":"th.d.ts","sourceRoot":"","sources":["../../src/backward/th.ts"],"names":[],"mappings":"AAAA;;;;;;GAMG;AACH,OAAO,KAAK,EAAE,eAAe,EAAE,MAAM,aAAa,CAAC;AAmBnD;;;;;;;;;;;;;;GAcG;AACH,wBAAgB,OAAO,CAAC,CAAC,EAAE,MAAM,EAAE,CAAC,EAAE,MAAM,GAAG,eAAe,CA8D7D"}
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+ {"version":3,"file":"th.d.ts","sourceRoot":"","sources":["../../src/backward/th.ts"],"names":[],"mappings":"AAAA;;;;;;GAMG;AACH,OAAO,KAAK,EAAE,eAAe,EAAE,MAAM,aAAa,CAAC;AAqBnD;;;;;;;;;;;;;;GAcG;AACH,wBAAgB,OAAO,CAAC,CAAC,EAAE,MAAM,EAAE,CAAC,EAAE,MAAM,GAAG,eAAe,CA8F7D"}
package/dist/backward/th.js CHANGED
@@ -8,7 +8,9 @@ import { region5 } from '../regions/region5.js';
8
8
  import { boundary23_T_to_P } from '../regions/boundaries.js';
9
9
  import { saturationPressure } from '../regions/region4.js';
10
10
  import { mixSaturationState, qualityFromSaturationProperty, saturationEndpointsAtTemperature, } from '../saturation/common.js';
11
+ import { assertRegion4StateAllowed } from '../saturation/region4-boundaries.js';
11
12
  import { solveFixedTemperaturePressure } from './fixed-temperature-solver.js';
13
+ import { validateBackwardState } from './solution-validation.js';
12
14
  const extractH = (s) => s.enthalpy;
13
15
  /**
14
16
  * Solve for full basic thermodynamic state from temperature and enthalpy.
@@ -38,28 +40,56 @@ export function solveTH(T, h) {
38
40
  const region = detectRegionTH(T, h);
39
41
  switch (region) {
40
42
  case Region.Region1:
41
- return solveFixedTemperaturePressure(region1, T, h, saturationPressure(T), C.P_MAX, extractH, 'solveTH');
43
+ return validateBackwardState(solveFixedTemperaturePressure(region1, T, h, saturationPressure(T), C.P_MAX, extractH, 'solveTH'), [
44
+ { label: 'temperature', expected: T },
45
+ { label: 'enthalpy', expected: h },
46
+ ], {
47
+ solverName: 'solveTH',
48
+ expectedRegion: Region.Region1,
49
+ });
42
50
  case Region.Region2: {
43
51
  const upper = T <= C.Tc
44
52
  ? saturationPressure(T)
45
53
  : T <= C.B23_T_MAX
46
54
  ? boundary23_T_to_P(T)
47
55
  : C.P_MAX;
48
- return solveFixedTemperaturePressure(region2, T, h, C.P_MIN, upper, extractH, 'solveTH');
56
+ return validateBackwardState(solveFixedTemperaturePressure(region2, T, h, C.P_MIN, upper, extractH, 'solveTH'), [
57
+ { label: 'temperature', expected: T },
58
+ { label: 'enthalpy', expected: h },
59
+ ], {
60
+ solverName: 'solveTH',
61
+ expectedRegion: Region.Region2,
62
+ });
49
63
  }
50
64
  case Region.Region3: {
51
65
  const lower = T <= C.Tc
52
66
  ? saturationPressure(T)
53
67
  : boundary23_T_to_P(T);
54
- return solveFixedTemperaturePressure(solveRegion3PTBasic, T, h, lower, C.P_MAX, extractH, 'solveTH');
68
+ return validateBackwardState(solveFixedTemperaturePressure(solveRegion3PTBasic, T, h, lower, C.P_MAX, extractH, 'solveTH'), [
69
+ { label: 'temperature', expected: T },
70
+ { label: 'enthalpy', expected: h },
71
+ ], {
72
+ solverName: 'solveTH',
73
+ expectedRegion: Region.Region3,
74
+ });
55
75
  }
56
76
  case Region.Region4: {
57
77
  const endpoints = saturationEndpointsAtTemperature(T);
78
+ assertRegion4StateAllowed(endpoints.pressure, endpoints.temperature, 'solveTH');
58
79
  const x = qualityFromSaturationProperty(endpoints.liquid.enthalpy, endpoints.vapor.enthalpy, h);
59
- return mixSaturationState(endpoints, x);
80
+ return validateBackwardState(mixSaturationState(endpoints, x), [
81
+ { label: 'temperature', expected: T },
82
+ { label: 'enthalpy', expected: h },
83
+ ], { solverName: 'solveTH', expectedRegion: Region.Region4 });
60
84
  }
61
85
  case Region.Region5:
62
- return solveFixedTemperaturePressure(region5, T, h, C.P_MIN, C.R5_P_MAX, extractH, 'solveTH');
86
+ return validateBackwardState(solveFixedTemperaturePressure(region5, T, h, C.P_MIN, C.R5_P_MAX, extractH, 'solveTH'), [
87
+ { label: 'temperature', expected: T },
88
+ { label: 'enthalpy', expected: h },
89
+ ], {
90
+ solverName: 'solveTH',
91
+ expectedRegion: Region.Region5,
92
+ });
63
93
  default:
64
94
  throw new IF97Error(`solveTH cannot determine a valid IF97 state for T=${T} K, h=${h} kJ/kg`);
65
95
  }
package/dist/backward/th.js.map CHANGED
@@ -1 +1 @@
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package/dist/backward/tolerances.d.ts ADDED
@@ -0,0 +1,6 @@
1
+ export type BackwardToleranceLabel = 'pressure' | 'temperature' | 'enthalpy' | 'entropy';
2
+ export declare const BACKWARD_REGION4_QUALITY_TOLERANCE = 0.000001;
3
+ export declare function backwardConstraintTolerance(label: BackwardToleranceLabel, expected: number): number;
4
+ export declare function region4SaturationPressureTolerance(pressure: number): number;
5
+ export declare function backwardSpecificVolumeTolerance(expected: number): number;
6
+ //# sourceMappingURL=tolerances.d.ts.map
package/dist/backward/tolerances.d.ts.map ADDED
@@ -0,0 +1 @@
1
+ {"version":3,"file":"tolerances.d.ts","sourceRoot":"","sources":["../../src/backward/tolerances.ts"],"names":[],"mappings":"AAAA,MAAM,MAAM,sBAAsB,GAAG,UAAU,GAAG,aAAa,GAAG,UAAU,GAAG,SAAS,CAAC;AAEzF,eAAO,MAAM,kCAAkC,WAAO,CAAC;AAEvD,wBAAgB,2BAA2B,CACzC,KAAK,EAAE,sBAAsB,EAC7B,QAAQ,EAAE,MAAM,GACf,MAAM,CAYR;AAED,wBAAgB,kCAAkC,CAAC,QAAQ,EAAE,MAAM,GAAG,MAAM,CAE3E;AAED,wBAAgB,+BAA+B,CAAC,QAAQ,EAAE,MAAM,GAAG,MAAM,CAExE"}
package/dist/backward/tolerances.js ADDED
@@ -0,0 +1,21 @@
1
+ export const BACKWARD_REGION4_QUALITY_TOLERANCE = 1e-6;
2
+ export function backwardConstraintTolerance(label, expected) {
3
+ switch (label) {
4
+ case 'pressure':
5
+ case 'temperature':
6
+ return 1e-9 * Math.max(1, Math.abs(expected));
7
+ case 'enthalpy':
8
+ return 1e-4 * Math.max(1, Math.abs(expected));
9
+ case 'entropy':
10
+ return 1e-6 * Math.max(1, Math.abs(expected));
11
+ default:
12
+ return 1e-9;
13
+ }
14
+ }
15
+ export function region4SaturationPressureTolerance(pressure) {
16
+ return 1e-8 * Math.max(1, Math.abs(pressure));
17
+ }
18
+ export function backwardSpecificVolumeTolerance(expected) {
19
+ return 1e-6 * Math.max(1, Math.abs(expected));
20
+ }
21
+ //# sourceMappingURL=tolerances.js.map
package/dist/backward/tolerances.js.map ADDED
@@ -0,0 +1 @@
1
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package/dist/backward/ts.d.ts.map CHANGED
@@ -1 +1 @@
1
- {"version":3,"file":"ts.d.ts","sourceRoot":"","sources":["../../src/backward/ts.ts"],"names":[],"mappings":"AAAA;;;;;;GAMG;AACH,OAAO,KAAK,EAAE,eAAe,EAAE,MAAM,aAAa,CAAC;AAmBnD;;;;;;;;;;;;;;GAcG;AACH,wBAAgB,OAAO,CAAC,CAAC,EAAE,MAAM,EAAE,CAAC,EAAE,MAAM,GAAG,eAAe,CA8D7D"}
1
+ {"version":3,"file":"ts.d.ts","sourceRoot":"","sources":["../../src/backward/ts.ts"],"names":[],"mappings":"AAAA;;;;;;GAMG;AACH,OAAO,KAAK,EAAE,eAAe,EAAE,MAAM,aAAa,CAAC;AAqBnD;;;;;;;;;;;;;;GAcG;AACH,wBAAgB,OAAO,CAAC,CAAC,EAAE,MAAM,EAAE,CAAC,EAAE,MAAM,GAAG,eAAe,CA8F7D"}
package/dist/backward/ts.js CHANGED
@@ -8,7 +8,9 @@ import { region5 } from '../regions/region5.js';
8
8
  import { boundary23_T_to_P } from '../regions/boundaries.js';
9
9
  import { saturationPressure } from '../regions/region4.js';
10
10
  import { mixSaturationState, qualityFromSaturationProperty, saturationEndpointsAtTemperature, } from '../saturation/common.js';
11
+ import { assertRegion4StateAllowed } from '../saturation/region4-boundaries.js';
11
12
  import { solveFixedTemperaturePressure } from './fixed-temperature-solver.js';
13
+ import { validateBackwardState } from './solution-validation.js';
12
14
  const extractS = (s) => s.entropy;
13
15
  /**
14
16
  * Solve for full basic thermodynamic state from temperature and entropy.
@@ -38,28 +40,56 @@ export function solveTS(T, s) {
38
40
  const region = detectRegionTS(T, s);
39
41
  switch (region) {
40
42
  case Region.Region1:
41
- return solveFixedTemperaturePressure(region1, T, s, saturationPressure(T), C.P_MAX, extractS, 'solveTS');
43
+ return validateBackwardState(solveFixedTemperaturePressure(region1, T, s, saturationPressure(T), C.P_MAX, extractS, 'solveTS'), [
44
+ { label: 'temperature', expected: T },
45
+ { label: 'entropy', expected: s },
46
+ ], {
47
+ solverName: 'solveTS',
48
+ expectedRegion: Region.Region1,
49
+ });
42
50
  case Region.Region2: {
43
51
  const upper = T <= C.Tc
44
52
  ? saturationPressure(T)
45
53
  : T <= C.B23_T_MAX
46
54
  ? boundary23_T_to_P(T)
47
55
  : C.P_MAX;
48
- return solveFixedTemperaturePressure(region2, T, s, C.P_MIN, upper, extractS, 'solveTS');
56
+ return validateBackwardState(solveFixedTemperaturePressure(region2, T, s, C.P_MIN, upper, extractS, 'solveTS'), [
57
+ { label: 'temperature', expected: T },
58
+ { label: 'entropy', expected: s },
59
+ ], {
60
+ solverName: 'solveTS',
61
+ expectedRegion: Region.Region2,
62
+ });
49
63
  }
50
64
  case Region.Region3: {
51
65
  const lower = T <= C.Tc
52
66
  ? saturationPressure(T)
53
67
  : boundary23_T_to_P(T);
54
- return solveFixedTemperaturePressure(solveRegion3PTBasic, T, s, lower, C.P_MAX, extractS, 'solveTS');
68
+ return validateBackwardState(solveFixedTemperaturePressure(solveRegion3PTBasic, T, s, lower, C.P_MAX, extractS, 'solveTS'), [
69
+ { label: 'temperature', expected: T },
70
+ { label: 'entropy', expected: s },
71
+ ], {
72
+ solverName: 'solveTS',
73
+ expectedRegion: Region.Region3,
74
+ });
55
75
  }
56
76
  case Region.Region4: {
57
77
  const endpoints = saturationEndpointsAtTemperature(T);
78
+ assertRegion4StateAllowed(endpoints.pressure, endpoints.temperature, 'solveTS');
58
79
  const x = qualityFromSaturationProperty(endpoints.liquid.entropy, endpoints.vapor.entropy, s);
59
- return mixSaturationState(endpoints, x);
80
+ return validateBackwardState(mixSaturationState(endpoints, x), [
81
+ { label: 'temperature', expected: T },
82
+ { label: 'entropy', expected: s },
83
+ ], { solverName: 'solveTS', expectedRegion: Region.Region4 });
60
84
  }
61
85
  case Region.Region5:
62
- return solveFixedTemperaturePressure(region5, T, s, C.P_MIN, C.R5_P_MAX, extractS, 'solveTS');
86
+ return validateBackwardState(solveFixedTemperaturePressure(region5, T, s, C.P_MIN, C.R5_P_MAX, extractS, 'solveTS'), [
87
+ { label: 'temperature', expected: T },
88
+ { label: 'entropy', expected: s },
89
+ ], {
90
+ solverName: 'solveTS',
91
+ expectedRegion: Region.Region5,
92
+ });
63
93
  default:
64
94
  throw new IF97Error(`solveTS cannot determine a valid IF97 state for T=${T} K, s=${s} kJ/(kg·K)`);
65
95
  }
package/dist/backward/ts.js.map CHANGED
@@ -1 +1 @@
1
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package/dist/constants.d.ts CHANGED
@@ -4,19 +4,37 @@
4
4
  * Physical constants, critical point properties, and range limits
5
5
  * for the IAPWS Industrial Formulation 1997.
6
6
  */
7
- /** Specific gas constant for water [kJ/(kg·K)] */
7
+ /** Specific gas constant for water [kJ/(kg·K)].
8
+ * IAPWS-IF97, §2 (Table 1). Fixed value for IF97 internal consistency;
9
+ * differs from the IAPWS-95 / CODATA value. */
8
10
  export declare const R = 0.461526;
9
11
  /** Critical temperature [K] */
10
12
  export declare const Tc = 647.096;
11
13
  /** Temperature exclusion half-band around the critical point [K] */
12
14
  export declare const CRITICAL_T_EXCLUSION_BAND = 0.001;
15
+ /** Region 4 endpoint snap tolerance for temperatures [K] */
16
+ export declare const REGION4_TEMPERATURE_TOLERANCE = 1e-9;
17
+ /** Safety margin used when clamping Region 4 temperatures below Tc [K] */
18
+ export declare const REGION4_SUBCRITICAL_TEMPERATURE_MARGIN = 1e-8;
13
19
  /** Critical pressure [MPa] */
14
20
  export declare const Pc = 22.064;
21
+ /** Region 4 endpoint snap tolerance for pressures [MPa] */
22
+ export declare const REGION4_PRESSURE_TOLERANCE = 1e-9;
23
+ /** Tolerance for identifying the critical h-s endpoint in Region 4 */
24
+ export declare const REGION4_CRITICAL_HS_TOLERANCE = 0.000001;
25
+ /** Residual tolerance for Region 4 h-s temperature inversion */
26
+ export declare const REGION4_HS_RESIDUAL_TOLERANCE = 1e-10;
27
+ /** Scan resolution used when bracketing Region 4 h-s temperature roots */
28
+ export declare const REGION4_HS_BRACKET_SEGMENTS = 256;
15
29
  /** Critical density [kg/m³] */
16
30
  export declare const RHOc = 322;
17
31
  /** Triple point pressure [MPa] */
18
32
  export declare const Pt = 0.000611657;
19
- /** Minimum pressure [MPa] */
33
+ /** Triple point temperature [K] */
34
+ export declare const Tt = 273.16;
35
+ /** Minimum pressure [MPa].
36
+ * Derived: Psat(T_MIN) = Psat(273.15 K) via Eq. 30. Below the triple-point
37
+ * pressure Pt because T_MIN (0 °C) < Tt (0.01 °C). */
20
38
  export declare const P_MIN = 0.000611212677444;
21
39
  /** Maximum pressure [MPa] */
22
40
  export declare const P_MAX = 100;
@@ -36,9 +54,13 @@ export declare const H_MAX = 7376.980263598506;
36
54
  export declare const R2_T_MIN = 623.15;
37
55
  /** Region 2 maximum temperature for backward eqs [K] (1073.15 K = 800 °C) */
38
56
  export declare const R2_T_MAX = 1073.15;
39
- /** Region 2 critical entropy boundary [kJ/(kg·K)] */
57
+ /** Region 2 subregion boundary entropy [kJ/(kg·K)].
58
+ * Divides R2a from R2b/R2c in the h-s plane.
59
+ * Ref: IAPWS Supplementary Release on Backward Equations for Region 2, §6.3 */
40
60
  export declare const R2_S_CRT = 5.85;
41
- /** Region 2 critical pressure boundary [MPa] */
61
+ /** Region 2 subregion boundary pressure [MPa].
62
+ * Divides R2a from R2b/R2c.
63
+ * Ref: IAPWS Supplementary Release on Backward Equations for Region 2, §6.3 */
42
64
  export declare const R2_P_CRT = 4;
43
65
  /** B23 minimum pressure [MPa] */
44
66
  export declare const B23_P_MIN = 16.5291642526;
@@ -56,12 +78,12 @@ export declare const R5_T_MIN = 1073.15;
56
78
  export declare const R5_P_MAX = 50;
57
79
  /** Region 5 maximum temperature [K] */
58
80
  export declare const R5_T_MAX = 2273.15;
59
- /** B23 minimum entropy [kJ/(kg·K)] */
60
- export declare const B23_S_MIN = 5.048096828;
61
- /** B23 maximum entropy [kJ/(kg·K)] */
62
- export declare const B23_S_MAX = 5.260578707;
63
- /** B23 minimum enthalpy [kJ/kg] */
64
- export declare const B23_H_MIN = 2563.592004;
65
- /** B23 maximum enthalpy [kJ/kg] */
66
- export declare const B23_H_MAX = 2812.942061;
81
+ /** Minimum entropy along the B23 curve [kJ/(kg·K)], at T ≈ 777 K */
82
+ export declare const B23_S_CURVE_MIN = 5.048096828;
83
+ /** Maximum entropy along the B23 curve [kJ/(kg·K)], at T ≈ 644 K */
84
+ export declare const B23_S_CURVE_MAX = 5.260578707;
85
+ /** Minimum enthalpy along the B23 curve [kJ/kg], at T = 623.15 K (currently unused) */
86
+ export declare const B23_H_CURVE_MIN = 2563.592004;
87
+ /** Maximum enthalpy along the B23 curve [kJ/kg], at T = 863.15 K (currently unused) */
88
+ export declare const B23_H_CURVE_MAX = 2812.942061;
67
89
  //# sourceMappingURL=constants.d.ts.map
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package/dist/constants.js CHANGED
@@ -5,22 +5,40 @@
5
5
  * for the IAPWS Industrial Formulation 1997.
6
6
  */
7
7
  // ─── Fundamental Constants ──────────────────────────────────────────────────
8
- /** Specific gas constant for water [kJ/(kg·K)] */
8
+ /** Specific gas constant for water [kJ/(kg·K)].
9
+ * IAPWS-IF97, §2 (Table 1). Fixed value for IF97 internal consistency;
10
+ * differs from the IAPWS-95 / CODATA value. */
9
11
  export const R = 0.461526;
10
12
  // ─── Critical Point ─────────────────────────────────────────────────────────
11
13
  /** Critical temperature [K] */
12
14
  export const Tc = 647.096;
13
15
  /** Temperature exclusion half-band around the critical point [K] */
14
16
  export const CRITICAL_T_EXCLUSION_BAND = 1e-3;
17
+ /** Region 4 endpoint snap tolerance for temperatures [K] */
18
+ export const REGION4_TEMPERATURE_TOLERANCE = 1e-9;
19
+ /** Safety margin used when clamping Region 4 temperatures below Tc [K] */
20
+ export const REGION4_SUBCRITICAL_TEMPERATURE_MARGIN = 1e-8;
15
21
  /** Critical pressure [MPa] */
16
22
  export const Pc = 22.064;
23
+ /** Region 4 endpoint snap tolerance for pressures [MPa] */
24
+ export const REGION4_PRESSURE_TOLERANCE = 1e-9;
25
+ /** Tolerance for identifying the critical h-s endpoint in Region 4 */
26
+ export const REGION4_CRITICAL_HS_TOLERANCE = 1e-6;
27
+ /** Residual tolerance for Region 4 h-s temperature inversion */
28
+ export const REGION4_HS_RESIDUAL_TOLERANCE = 1e-10;
29
+ /** Scan resolution used when bracketing Region 4 h-s temperature roots */
30
+ export const REGION4_HS_BRACKET_SEGMENTS = 256;
17
31
  /** Critical density [kg/m³] */
18
32
  export const RHOc = 322;
19
33
  // ─── Triple Point ───────────────────────────────────────────────────────────
20
34
  /** Triple point pressure [MPa] */
21
35
  export const Pt = 0.000611657;
36
+ /** Triple point temperature [K] */
37
+ export const Tt = 273.16;
22
38
  // ─── Overall Validity Ranges ────────────────────────────────────────────────
23
- /** Minimum pressure [MPa] */
39
+ /** Minimum pressure [MPa].
40
+ * Derived: Psat(T_MIN) = Psat(273.15 K) via Eq. 30. Below the triple-point
41
+ * pressure Pt because T_MIN (0 °C) < Tt (0.01 °C). */
24
42
  export const P_MIN = 0.000611212677444;
25
43
  /** Maximum pressure [MPa] */
26
44
  export const P_MAX = 100.0;
@@ -41,9 +59,13 @@ export const H_MAX = 7376.980263598506;
41
59
  export const R2_T_MIN = 623.15;
42
60
  /** Region 2 maximum temperature for backward eqs [K] (1073.15 K = 800 °C) */
43
61
  export const R2_T_MAX = 1073.15;
44
- /** Region 2 critical entropy boundary [kJ/(kg·K)] */
62
+ /** Region 2 subregion boundary entropy [kJ/(kg·K)].
63
+ * Divides R2a from R2b/R2c in the h-s plane.
64
+ * Ref: IAPWS Supplementary Release on Backward Equations for Region 2, §6.3 */
45
65
  export const R2_S_CRT = 5.85;
46
- /** Region 2 critical pressure boundary [MPa] */
66
+ /** Region 2 subregion boundary pressure [MPa].
67
+ * Divides R2a from R2b/R2c.
68
+ * Ref: IAPWS Supplementary Release on Backward Equations for Region 2, §6.3 */
47
69
  export const R2_P_CRT = 4.0;
48
70
  // ─── Region 2-3 Boundary ───────────────────────────────────────────────────
49
71
  /** B23 minimum pressure [MPa] */
@@ -64,13 +86,21 @@ export const R5_T_MIN = 1073.15;
64
86
  export const R5_P_MAX = 50;
65
87
  /** Region 5 maximum temperature [K] */
66
88
  export const R5_T_MAX = 2273.15;
67
- // ─── B23 Entropy/Enthalpy Boundaries ────────────────────────────────────────
68
- /** B23 minimum entropy [kJ/(kg·K)] */
69
- export const B23_S_MIN = 5.048096828;
70
- /** B23 maximum entropy [kJ/(kg·K)] */
71
- export const B23_S_MAX = 5.260578707;
72
- /** B23 minimum enthalpy [kJ/kg] */
73
- export const B23_H_MIN = 2563.592004;
74
- /** B23 maximum enthalpy [kJ/kg] */
75
- export const B23_H_MAX = 2812.942061;
89
+ // ─── B23 Curve Extrema (Entropy / Enthalpy) ────────────────────────────────
90
+ //
91
+ // These are the GLOBAL EXTREMA along the B23 boundary curve, NOT values at
92
+ // the curve endpoints. Entropy has a minimum at T ≈ 777 K and a maximum at
93
+ // T ≈ 644 K. Enthalpy is monotonic: min at the low-T endpoint (623.15 K),
94
+ // max at the high-T endpoint (863.15 K).
95
+ //
96
+ // Ref: Computed from Region 2 properties evaluated along B23(T) for
97
+ // T ∈ [623.15, 863.15] K.
98
+ /** Minimum entropy along the B23 curve [kJ/(kg·K)], at T ≈ 777 K */
99
+ export const B23_S_CURVE_MIN = 5.048096828;
100
+ /** Maximum entropy along the B23 curve [kJ/(kg·K)], at T ≈ 644 K */
101
+ export const B23_S_CURVE_MAX = 5.260578707;
102
+ /** Minimum enthalpy along the B23 curve [kJ/kg], at T = 623.15 K (currently unused) */
103
+ export const B23_H_CURVE_MIN = 2563.592004;
104
+ /** Maximum enthalpy along the B23 curve [kJ/kg], at T = 863.15 K (currently unused) */
105
+ export const B23_H_CURVE_MAX = 2812.942061;
76
106
  //# sourceMappingURL=constants.js.map